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Hot-dip galvanization is a form of galvanization. It is the process of coating iron and steel with a layer of zinc by immersing the metal in a bath of molten zinc at a temperature of around 449 °C. When exposed to the atmosphere, the pure zinc reacts with oxygen to form zinc oxide (ZnO), which further reacts with carbon dioxide (CO2) to form zinc carbonate (ZnCO3), a usually dull grey, fairly strong material that protects the steel underneath from further corrosion in many circumstances
The process of hot-dip galvanizing results in a metallurgical bond between zinc and steel with a series of distinct iron-zinc alloys. The resulting coated steel can be used in much the same way as uncoated.
A typical hot-dip galvanizing line operates as follows:
Lead is often added to the molten zinc bath to improve the fluidity of the bath (thus limiting excess zinc on the dipped product by improved drainage properties), helps prevent floating dross, makes dross recycling easier and protects the Pilling kettle from uneven heat distribution from the burners. Lead is either added to primary Z1 grade zinc or already contained in used secondary zinc. A third, declining method is to use low Z5 grade zinc.
Steel strip can be hot-dip galvanized in a continuous line. Hot-dip galvanized steel strip (also sometimes loosely referred to as galvanized iron) is extensively used for applications requiring the strength of steel combined with the resistance to corrosion of zinc. roofing and walling, safety barriers, handrails, consumer appliances and automotive body parts. One common use is in metal pails. Galvanised steel is also used in most heating and cooling duct systems in buildings
Individual metal articles, such as steel girders or wrought iron gates, can be hot-dip galvanized by a process called batch galvanizing. Other modern techniques have largely replaced hot-dip for these sorts of roles. This includes electrogalvanizing, which deposits the layer of zinc from an aqueous electrolyte by electroplating, forming a thinner and much stronger bond.